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Engineered cytochrome P450PL2 enables kinetically enantioselective hydroxylation of (2-chloropropyl)benzene derivatives, achieving up to 99:1 enantiomeric ratio and >99:1 diastereomeric ratio.
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Oxidative Organic Chemistry Reactions
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A spatially decoupled Fe-Mo dual-site nanoconfined catalyst (FeMo-NC) reduces the C–H bond dissociation barrier by 18.3% and enables controlled phenol oligomerization.
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Contact-electro-catalysis at the PTFE–H2O interface enables hydroxyl radical (·OH)-mediated hydroxylation of aromatic C–H bonds under ambient conditions, achieving up to 210.90 μmol·gcat−1·h−1.
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